1-Chloromethylnaphthalene → O-(naphthalen-1-ylmethyl)hydroxylamine

反応式

[OH:1][N:2]1C(=O)C2=CC=CC=C2C1=O.Cl[CH2:14][C:15]1[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][CH:16]=1>>[C:15]1([CH2:14][O:1][NH2:2])[C:24]2[C:19](=[CH:20][CH:21]=[CH:22][CH:23]=2)[CH:18]=[CH:17][CH:16]=1

参加物

反応物 2

HCID 68451-Chloromethylnaphthalene

HCID 10665N-Hydroxyphthalimide

生成物 1

HCID 15009996O-(naphthalen-1-ylmethyl)hydroxylamine

実験手順

Prepared by a similar procedure as described for preparation 13. Starting materials: N-Hydroxyphthalimide and 1-chloromethyl-naphthalen. 13C-NMR (DMSO-d6) δ 133.5, 133.2, 131.4, 128.2, 126.8, 126.7, 126.0, 125.6, 125.2, 124.1, 75.4.

後処理

customPrepared by a similar procedure
customas described for preparation 13

出典と根拠

ORDレコード: ord-bca39f7810714098a080e87e71027dca
出典データセット: uspto-grants-2011_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US08034811B2

反応ノート

読み込み中…

参加物