Dimethyl Sulfoxide → 1,1'-Disulfanediylbis(2-chlorobenzene)

HRID 1677889

反応式

HRID 1677889 の反応式
C[Si](C)(C)N[Si](C)(C)C.[Cl:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[SH:17].C[S:19]([CH3:21])=O>C(#N)C>[Cl:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=1[S:17][S:19][C:21]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1[Cl:10]

参加物

5

反応物 3

HCID 679Dimethyl SulfoxideHCID 13838HexamethyldisilazaneHCID 80599o-Chlorothiophenol

生成物 1

HCID 2334821,1'-Disulfanediylbis(2-chlorobenzene)

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

Hexamethyldisilazane (4.4 ml) was added to a stirred solution of 2-chlorobenzenethiol (2.0 ml) and DMSO (3.7 ml) in dry acetonitrile at room temperature. After 2 h the white precipitate was filtered and washed (cold acetonitrile) to give the sub-title compound as a white solid (2.27 g).

後処理

  1. filtrationAfter 2 h the white precipitate was filtered
  2. washwashed (cold acetonitrile)

出典と根拠

ORDレコード
ord-f4d09ce3c578485aa0a9717be143ef9e
出典データセット
uspto-grants-2011_08
特許番号
US08008350B2

関連ノート

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