Acetic Acid → Acetic acid, 2-(4-nitrophenyl)hydrazide

HRID 1679246ノート

反応式

HRID 1679246 の反応式
[N+:1]([C:4]1[CH:9]=[CH:8][C:7]([NH:10][NH2:11])=[CH:6][CH:5]=1)([O-:3])=[O:2].[C:12](O)(=[O:14])[CH3:13]>>[C:12]([NH:11][NH:10][C:7]1[CH:6]=[CH:5][C:4]([N+:1]([O-:3])=[O:2])=[CH:9][CH:8]=1)(=[O:14])[CH3:13]

参加物

3

反応物 2

HCID 176Acetic AcidHCID 3310889(4-Nitrophenyl)hydrazine

生成物 1

HCID 3404344Acetic acid, 2-(4-nitrophenyl)hydrazide

反応条件

温度
90 °C

実験手順

4-Nitrophenylhydrazine (15.0 g, 0.10 mole) and acetic acid (24.0 g, 0.40 mole) were mixed in a flask equipped with a stirrer and reflux condenser and heated at about 90° C for one hour. The solid mass was collected, washed with water, and then dissolved in hot ethanol. The resulting solution was chilled in ice to give tan needles. Yield 14.4 g (74%), mp 207°-209° C.

後処理

  1. customequipped with a stirrer
  2. temperaturereflux condenser
  3. customThe solid mass was collected
  4. washwashed with water
  5. dissolutiondissolved in hot ethanol
  6. temperatureThe resulting solution was chilled in ice
  7. customto give tan needles

出典と根拠

ORDレコード
ord-dfa883a8947146d0a3519bd8d60be686
出典データセット
uspto-grants-1978_03
特許番号
US04080207

反応ノート

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