Chloral → 3-(1-Hydroxy-2,2,2-trichloroethylmercapto)-4-n-butyl-1,2,4-triazole
反応式
[SH:1][C:2]1[N:6]([CH2:7][CH2:8][CH2:9][CH3:10])[CH:5]=[N:4][N:3]=1.[O:11]=[CH:12][C:13]([Cl:16])([Cl:15])[Cl:14]>C1C=CC=CC=1>[OH:11][CH:12]([S:1][C:2]1[N:6]([CH2:7][CH2:8][CH2:9][CH3:10])[CH:5]=[N:4][N:3]=1)[C:13]([Cl:16])([Cl:15])[Cl:14]参加物
4
実験手順
3-Mercapto-4-n-butyl-1,2,4-triazole (2.0 g. or 0.127 mole) and chloral (3.68 g. or 0.0254 mole) were heated in benzene (30 ml.) until a precipitate formed (10 minutes). The mixture was cooled, the precipitate was collected, dried, and recrystallized from ether-hexane to give 3-(1-hydroxy-2,2,2-trichloroethylmercapto)-4-n-butyl-1,2,4-triazole melting at 95°-97° C. The structure was confirmed by its nuclear magnetic resonance spectrum.
後処理
- customformed (10 minutes)
- temperatureThe mixture was cooled
- customthe precipitate was collected
- customdried
- customrecrystallized from ether-hexane
出典と根拠
- ORDレコード
- ord-7ead255e26344e598ccbacb7c321debd
- 出典データセット
- uspto-grants-1981_06
- 特許番号
- US04271308
反応ノート
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