Allyl chloride → Trichloro(2,4,4-trimethylpentyl)silane

HRID 1680910

反応式

HRID 1680910 の反応式
[Cl:1][SiH:2]([Cl:4])[Cl:3].[CH3:5][C:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])=[CH2:7].CC(C)=CC(C)(C)C.C(Cl)C=C>>[CH3:5][CH:6]([CH2:8][C:9]([CH3:12])([CH3:11])[CH3:10])[CH2:7][Si:2]([Cl:4])([Cl:3])[Cl:1]

参加物

5

反応物 4

HCID 7850Allyl chlorideHCID 78682,4,4-Trimethyl-1-pentene2 回HCID 78692,4,4-Trimethyl-2-penteneHCID 24811Trichlorosilane3 回

生成物 1

HCID 86714Trichloro(2,4,4-trimethylpentyl)silane

実験手順

The process described in Example 2 is repeated, except that 1.2 liters of trichlorosilane, 1.8 liters of diisobutylene (a mixture of 2,4,4-trimethylpentene-1 and 2,4,4-trimethylpentene-2) and 10 ml of the catalytic solution are substituted for the trichlorosilane, allyl chloride and catalytic solution. About 98.6 mol percent of the trichlorosilane employed is reacted and 11.6 moles per hour of 2,4,4-trimethylpentyltrichlorosilane are obtained.

出典と根拠

ORDレコード
ord-b643a7355bf94b5bb75ce21e901fbfa5
出典データセット
uspto-grants-1981_06
特許番号
US04276426

関連ノート

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