Benzyl acetone → 4-[2-(4-Phenylbutan-2-ylidene)hydrazinyl]pyridin-2(1H)-one

HRID 1686021ノート

反応式

HRID 1686021 の反応式
[NH:1]([C:3]1[CH:8]=[CH:7][NH:6][C:5](=[O:9])[CH:4]=1)[NH2:2].[CH2:10]([CH2:17][C:18](=O)[CH3:19])[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>>[CH3:19][C:18](=[N:2][NH:1][C:3]1[CH:8]=[CH:7][NH:6][C:5](=[O:9])[CH:4]=1)[CH2:17][CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1

参加物

3

反応物 2

HCID 17355Benzyl acetoneHCID 136108294-Hydrazinylpyridin-2(1H)-one

生成物 1

HCID 714120494-[2-(4-Phenylbutan-2-ylidene)hydrazinyl]pyridin-2(1H)-one

実験手順

In accordance with the same procedures as in Step 2 of Preparation 1, except for using 4-hydrazino-1H-pyridin-2-one (5.39 g, 43.1 mmol) prepared in Step 1 of Preparation 1 and benzylacetone (9.70 ml, 64.6 mmol), the titled compound was obtained as a white solid. (Yield: 66.5%) The product was used in the subsequent reaction without further purification.

後処理

  1. customIn accordance with the same procedures as in Step 2 of Preparation 1

出典と根拠

ORDレコード
ord-35de0e18615f4d3f9fefef6ef3bcfadf
出典データセット
uspto-grants-2012_04
特許番号
US08148529B2

反応ノート

読み込み中…