4-Chlorobenzotrichloride → HCID 14786574、化合物

HRID 1701109

反応式

HRID 1701109 の反応式
[Cl-].[Al+3].[Cl-].[Cl-].S(Cl)SCl.S(Cl)(Cl)(=O)=O.[Cl:14]C1C=CC(C(Cl)(Cl)Cl)=CC=1.[Cl:25][C:26]1[CH:27]=[C:28]([C:33]([Cl:36])([Cl:35])[Cl:34])[CH:29]=[CH:30][C:31]=1[Cl:32]>>[Cl:14][C:29]1[CH:30]=[C:31]([Cl:32])[C:26]([Cl:25])=[CH:27][C:28]=1[C:33]([Cl:36])([Cl:34])[Cl:35]

参加物

6

反応物 5

HCID 212774-Chlorobenzotrichloride2 回HCID 24648Sulfuryl chloride2 回HCID 24807Sulfur monochlorideHCID 256083,4-DichlorophenyltrichloromethaneHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 14786574HCID 14786574、化合物収率 47%

実験手順

A solution of 4.6 g (34 mmol) of aluminum chloride and 4.6 g (34 mmol) of disulphur dichloride in 344 g (2.55 mol) of sulphuryl chloride was added dropwise to a mixture of 57.5 g (250 mmol) of p-chlorobenzotrichloride and 115 g (850 mmol) of sulphuryl chloride at 40° C. The reaction mixture was further processed in the manner described in Example 5, that is to say that, after the working up, unreacted p-chlorobenzotrichloride and 3,4-dichlorobenzotrichloride were separated off by distillation and fed to renewed chlorination with sulphuryl chloride under the conditions given here. By distillation of the combined sump fractions, 2,4,5-trichlorobenzotrichloride was obtained in a yield of 47% of theory.

後処理

  1. customwere separated off by distillation and fed
  2. distillationBy distillation of the combined sump fractions

出典と根拠

ORDレコード
ord-52cf572afbf74898ac1c65e3b0945300
出典データセット
uspto-grants-1980_03
特許番号
US04191711

関連ノート

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