Potassium Hydroxide → Acetic acid, ((5,6,7,8-tetrahydro-4-(2-thienylcarbonyl)-1-naphthalenyl)oxy)-
反応式
[C:1]1([C:6]([C:8]2[C:17]3[CH2:16][CH2:15][CH2:14][CH2:13][C:12]=3[C:11]([O:18][CH2:19][C:20]([O:22]C)=[O:21])=[CH:10][CH:9]=2)=[O:7])[S:5][CH:4]=[CH:3][CH:2]=1.[OH-].[K+]>C(O)C.O>[C:1]1([C:6]([C:8]2[C:17]3[CH2:16][CH2:15][CH2:14][CH2:13][C:12]=3[C:11]([O:18][CH2:19][C:20]([OH:22])=[O:21])=[CH:10][CH:9]=2)=[O:7])[S:5][CH:4]=[CH:3][CH:2]=1参加物
5
実験手順
9 g of the ester according to (b) are dissolved in 100 ml aqueous ethanol. 1.8 g potassium hydroxide dissolved in 25 ml water are added and the mixture refluxed for 8 hours. The ethanol is evaporated and the remaining aqueous phase acidified by addition of mineral acid. The acid is extracted in ethyl ether.