Tert-Butylamine → HX-CH 44BS

HRID 1701953ノート

反応式

HRID 1701953 の反応式
[O:1]1[CH:3]([CH3:4])[CH:2]1[O:5][C:6]1[CH:11]=[CH:10][C:9]([C:12]2[N:21]([CH3:22])[C:20](=[O:23])[C:19]3[C:14](=[CH:15][CH:16]=[C:17]([O:24][CH3:25])[CH:18]=3)[N:13]=2)=[CH:8][CH:7]=1.[C:26]([NH2:30])([CH3:29])([CH3:28])[CH3:27]>>[OH:1][CH:3]([CH2:4][NH:30][C:26]([CH3:29])([CH3:28])[CH3:27])[CH2:2][O:5][C:6]1[CH:7]=[CH:8][C:9]([C:12]2[N:21]([CH3:22])[C:20](=[O:23])[C:19]3[C:14](=[CH:15][CH:16]=[C:17]([O:24][CH3:25])[CH:18]=3)[N:13]=2)=[CH:10][CH:11]=1

参加物

3

反応物 2

HCID 6385Tert-ButylamineHCID 13688278HCID 13688278、化合物

生成物 1

HCID 63180HX-CH 44BS

実験手順

1.7 gm (5 mmols) of the epoxide obtained in (a) were heated in a steel cylinder with 17 ml of tert. butylamine at 120° C. for 3 hours. Thereafter, the excess amine was distilled off in vacuo, and the oily residue was recrystallized from acetone/ether.

後処理

  1. distillationThereafter, the excess amine was distilled off in vacuo
  2. customthe oily residue was recrystallized from acetone/ether

出典と根拠

ORDレコード
ord-f42c93d4b0784a0ea03d06b1c18ffb34
出典データセット
uspto-grants-1983_04
特許番号
US04379788

反応ノート

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