反応式
[O:1]([CH2:8][CH:9]([OH:12])[CH2:10][Cl:11])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.Cl[C:14]([O:16][CH2:17][CH2:18][Cl:19])=[O:15]>>[C:14](=[O:15])([O:12][CH:9]([CH2:8][O:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[CH2:10][Cl:11])[O:16][CH2:17][CH2:18][Cl:19]参加物
3
実験手順
By reacting 3-phenoxy-1-chloro-2-propanol with 2-chloroethyl chloroformate according to conventional chloroformate ester reaction procedures, 2-chloroethyl 3-phenoxy-1-chloro-2-propyl carbonate is obtained. When the latter compound is heated in the presence of a phosphonium or ammonium salt catalyst as shown in the foregoing examples, phenyl glycidyl ether is produced as the principal epoxide product.
出典と根拠
- ORDレコード
- ord-ee227660f37a44498bf640fc72e565fe
- 出典データセット
- uspto-grants-1982_09
- 特許番号
- US04349482
関連ノート
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