Perfluorooctanesulfonic acid → HCID 20553275、化合物

HRID 1702957

反応式

HRID 1702957 の反応式
[CH:1]([C:4]1[CH:9]=[CH:8][C:7]([CH:10]([NH2:12])[CH3:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2].[F:13][C:14]([F:41])([S:37]([OH:40])(=[O:39])=[O:38])[C:15]([F:36])([F:35])[C:16]([F:34])([F:33])[C:17]([F:32])([F:31])[C:18]([F:30])([F:29])[C:19]([F:28])([F:27])[C:20]([F:26])([F:25])[C:21]([F:24])([F:23])[F:22]>C(O)C>[F:41][C:14]([F:13])([S:37]([O-:40])(=[O:39])=[O:38])[C:15]([F:35])([F:36])[C:16]([F:34])([F:33])[C:17]([F:31])([F:32])[C:18]([F:30])([F:29])[C:19]([F:28])([F:27])[C:20]([F:26])([F:25])[C:21]([F:24])([F:23])[F:22].[CH:1]([C:4]1[CH:9]=[CH:8][C:7]([CH:10]([NH3+:12])[CH3:11])=[CH:6][CH:5]=1)([CH3:3])[CH3:2]

参加物

4

反応物 2

HCID 74483Perfluorooctanesulfonic acidHCID 37280391-(4-Isopropylphenyl)ethanamine

生成物 1

HCID 20553275HCID 20553275、化合物

試薬・触媒・溶媒 1

HCID 702Ethanol溶媒

実験手順

The perfluoro-octylsulphonate salt was prepared by mixing a solution of 1-(4-isopropylphenyl)ethylamine (16.1 g) in ethanol (20 ml) with a solution of perfluoro-octylsulphonic acid (50 ml). The solution was evaporated to dryness and the residue was recrystallised from chloroform as soft colourless plates of 1-(4-isopropylphenyl) ethyl ammonium perfluoro-octyl sulphonate, melting point 158° C.(d). (Found: C 34.3; H 2.5; N 2.2%. C19H18F17NO3S requires: C 34.40; H 2.73; N 2.11%).

後処理

  1. customThe solution was evaporated to dryness
  2. customthe residue was recrystallised from chloroform as soft colourless plates of 1-(4-isopropylphenyl) ethyl ammonium perfluoro-octyl sulphonate, melting point 158° C.(d)

出典と根拠

ORDレコード
ord-6d585b59466345fe8cd212ca150b32da
出典データセット
uspto-grants-1982_09
特許番号
US04350644

関連ノート

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