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Acetyl chloride → Succinate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetyl chloride | HCID 6367 | — |
| 反応物 | Succinyl chloride | HCID 10970 | — |
| 反応物 | Pentanedioyl dichloride | HCID 17887 | — |
| 反応物 | Bruceolide | HCID 99531 | — |
| 反応物 | Methyl (1R,2S,3R,6R,8R,13S,14R,15R,16S,17R)-10,15,16-trihydroxy-9,13-dimethyl-3-(3-methylbut-2-enoyloxy)-4,11-dioxo-5,18-dioxapentacyclo[12.5.0.01,6.02,17.08,13]nonadec-9-ene-17-carboxylate | HCID 12302104 | — |
| 生成物 | Succinate | HCID 160419 | — |
| 生成物 | Glutarate(2-) | HCID 4418048 | — |
| 生成物 | 3,5-Dioxohexanoic acid | HCID 5459844 | — |
反応手順
In accordance with the above procedure, but where, in place of 3,4-dimethyl-2-pentenoyl chloride, there is utilized benzoyl chloride, trimethoxybenzoyl chloride or cinnamoyl chloride there is obtained the corresponding 3-ester or 3,15-diester. Similarly, but where, in place of bruceolide, there is utilized brusatol and as an acid chloride there is utilized succinoyl chloride, glutaroyl chloride and acetyl chloride, there is obtained 3,3-bisbrusatolyl succinate, 3,3-bisbrusatolyl glutarate and 3,11,12-brusatolyl triacetate, 3, 11, 12 bis brusatolyl triacetate can also be prepared by acetylation with pyridine in acetic anhydride.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04350638 |
| 出典データセット | uspto-grants-1982_09 |
| ORD ID | ord-233cfa63431c469c810679ed744ad36f |
| 出典メモ | uspto-grants-1982_09 |