化工社化工社 化学情報印刷レポート · 研究参考用
Hydrochloric Acid → 4-Decyloxybenzyl alcohol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Hydrochloric Acid | HCID 313 | — |
| 反応物 | Borane | HCID 6331 | — |
| 反応物 | 4-(Decyloxy)benzoic acid | HCID 138527 | — |
| 溶媒 | Water | HCID 962 | — |
| 溶媒 | Tetrahydrofuran | HCID 8028 | — |
| 生成物 | 4-Decyloxybenzyl alcohol | HCID 13079652 | — |
反応手順
To 100 ml. of 1.0 M borane in tetrahydrofuran cooled in an ice bath under nitrogen is added dropwise, 27.8 g. of p-decyloxybenzoic acid in 300 ml. of tetrahydrofuran over a period of 45 minutes. The mixture is stirred at room temperature for 6 hours and poured onto ice, diluted with water and 10 ml. of concentrated hydrochloric acid. The mixture is filtered and the solid washed with water to give white crystals. Recrystallization from ethanol gives white plates, m.p. 57.5°-59° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04350822 |
| 出典データセット | uspto-grants-1982_09 |
| ORD ID | ord-1886cca7e74b47babd18d00a53db5053 |
| 出典メモ | uspto-grants-1982_09 |