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p-Chlorothiophenol → 4-(p-Chlorophenylthio)butyl acetate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | p-Chlorothiophenol | HCID 7815 | — |
| 反応物 | Sodium Hydroxide | HCID 14798 | — |
| 反応物 | 1-Butanol, 4-chloro-, 1-acetate | HCID 23399 | — |
| 溶媒 | Ethanol | HCID 702 | — |
| 生成物 | 4-(p-Chlorophenylthio)butyl acetate | HCID 22762117 | — |
反応手順
A mixture of 144.6 g of p-chlorothiophenol, 150.6 g of 4-chlorobutyl acetate, 80 g of 50% aqueous solution of sodium hydroxide and 750 ml of ethyl alcohol was heated under reflux for 5 hours. The alcohol was distilled off and ether was added to the cool mixture. After washing with dilute sodium hydroxide solution and then water, the ether solution was dried, evaporated to dryness and distilled. The product was collected at 110°-116° and 0.01 mm, ND25 1.5480.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04124723 |
| 出典データセット | uspto-grants-1978_11 |
| ORD ID | ord-d70fea656dfc4dd2a8e3c7cf3700a245 |
| 出典メモ | uspto-grants-1978_11 |