Nalpha-(3-(acetylthio)-2-methoxycarbonylmethylpropanoyl]-L-lysine → Nalpha-[2-(carbamoylmethyl)-3-mercaptopropanoyl]-L-lysine

HRID 1704792ノート

反応式

HRID 1704792 の反応式
C([S:4][CH2:5][CH:6]([CH2:19][C:20]([O:22]C)=O)[C:7]([NH:9][C@H:10]([C:16]([OH:18])=[O:17])[CH2:11][CH2:12][CH2:13][CH2:14][NH2:15])=[O:8])(=O)C.C(SCC(CC(OC)=O)C([NH:32][C@H](C(O)=O)CCCNC(=N)N)=O)(=O)C>>[C:20]([CH2:19][CH:6]([CH2:5][SH:4])[C:7]([NH:9][C@H:10]([C:16]([OH:18])=[O:17])[CH2:11][CH2:12][CH2:13][CH2:14][NH2:15])=[O:8])(=[O:22])[NH2:32]

参加物

3

反応物 2

HCID 22803504Nalpha-(3-(acetylthio)-2-methoxycarbonylmethylpropanoyl]-L-lysineHCID 178500599HCID 178500599、化合物

生成物 1

HCID 22803502Nalpha-[2-(carbamoylmethyl)-3-mercaptopropanoyl]-L-lysine

実験手順

By substituting Nα -(3-(acetylthio)-2-methoxycarbonylmethylpropanoyl]-L-lysine for the Nα -[3-acetylthio-2-methoxycarbonylmethylpropanoyl]-L-arginine in the procedure of Example 19, Nα -[2-(carbamoylmethyl)-3-mercaptopropanoyl]-L-lysine is obtained.

出典と根拠

ORDレコード
ord-36086254ec23447989edf91513b117df
出典データセット
uspto-grants-1978_11
特許番号
US04127729

反応ノート

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