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Myristicin → Methyleugenol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Myristicin | HCID 4276 | — |
| 反応物 | Apiole | HCID 10659 | — |
| 反応物 | Tangeretin | HCID 68077 | — |
| 反応物 | Bergamottin | HCID 5471349 | — |
| 反応物 | (2S)-6-methyl-2-(4-methylcyclohex-3-en-1-yl)hept-5-en-2-ol | HCID 6097621 | — |
| 生成物 | Methyleugenol | HCID 7127 | — |
反応手順
Chemicals were purchased from Sigma-Aldrich Chemical Company (St. Louis, Mo.) unless noted. Plant oils were manufactured by Aura Cacia (Weaverville, Calif.). Juvocimene was synthesized as described (Mestres, R. and E. Munoz, 1996, Synthetic Comm., 26:1309-1319). Myristicin, apiole, bergamotin, tangeretin, bisabolol, and cucurbitacin were obtained from Indofine Chemical Company (Somerville, N.J.). Methyleugenol was provided by the Batelle Chemical Company (Columbus, Ohio). Man-made insecticides were purchased from Chem Service (West Chester, Pa.). The precocene-like suicide substrate 3,4-dimethoxyisopentenylphenol was prepared as described Bowers, W. S., et al., 1976, Science, 217:647-648) except that a 3,4-dimethoxylated reactant was used.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07790377B2 |
| 出典データセット | uspto-grants-2010_09 |
| ORD ID | ord-984e2a73d7d14cc7b3a454edf29d3d16 |
| 出典メモ | uspto-grants-2010_09 |