Ethyl (3-{4-[(diphenylmethylene)amino]phenyl}cyclohexyl)acetate → Ethyl ((3R)-3-{4-[(diphenylmethylene)amino]phenyl}cyclopentylidene)acetate
反応式
[C:1]1([C:7](=[N:14]C2C=CC(C3CCCC(CC(OCC)=O)C3)=CC=2)[C:8]2[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Br[C:34]1[CH:39]=[CH:38][C:37]([C@@H:40]2[CH2:44][CH2:43][C:42](=[CH:45][C:46]([O:48][CH2:49][CH3:50])=[O:47])[CH2:41]2)=[CH:36][CH:35]=1>>[C:1]1([C:7](=[N:14][C:34]2[CH:39]=[CH:38][C:37]([C@@H:40]3[CH2:44][CH2:43][C:42](=[CH:45][C:46]([O:48][CH2:49][CH3:50])=[O:47])[CH2:41]3)=[CH:36][CH:35]=2)[C:8]2[CH:9]=[CH:10][CH:11]=[CH:12][CH:13]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1参加物
3
実験手順
Following the procedure described for ethyl (3-{4-[(diphenylmethylene)amino]phenyl}cyclohexyl)acetate (Intermediate 89(iii)), replacing ethyl [3-(4-{[(trifluoromethyl)sulphonyl]oxy}phenyl)cyclohexyl]acetate with ethyl [(3R)-3-(4-bromophenyl)cyclopentylidene]acetate, the title compound was obtained; MS m/e MH+ 410.
出典と根拠
- ORDレコード
- ord-71abb45e57414977902083cd87627ec1