Toluene → HCID 54399221、化合物

HRID 1719573ノート

反応式

HRID 1719573 の反応式
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([SH:15])[C:6]=1[OH:16])([CH3:4])([CH3:3])[CH3:2].[C:17]([O:21][CH3:22])(=[O:20])[CH:18]=[CH2:19].C1(C)C=CC=CC=1>C(N(CC)CC)C>[CH3:22][O:21][C:17](=[O:20])[CH2:18][CH2:19][S:15][C:7]1[CH:8]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:10]=[C:5]([C:1]([CH3:4])([CH3:2])[CH3:3])[C:6]=1[OH:16]

参加物

5

反応物 3

HCID 1140TolueneHCID 7294Methyl AcrylateHCID 3041162Phenol, 2,2-bis(1,1-dimethylethyl)-6-mercapto-

生成物 1

HCID 54399221HCID 54399221、化合物収率 57.5%

試薬・触媒・溶媒 1

HCID 8471Triethylamine溶媒

実験手順

In a 50 ml flask under nitrogen, a mixture of 5.00 grams of 2,4-di-tert-butyl-6-mercaptophenol, 1.80 grams of methyl acrylate and 20 mls toluene was treated with 0.50 mls of triethylamine. After stirring for three hours at ambient temperature, the solvent was removed in vacuo. The residue was purified by chromatography on silica gel using toluene/heptane eluent to give 3.90 g (57% yield) of a colorless oil.

後処理

  1. customthe solvent was removed in vacuo
  2. customThe residue was purified by chromatography on silica gel

出典と根拠

ORDレコード
ord-eb1447d37e394e3080212b5acbb4ef17
出典データセット
uspto-grants-1985_09
特許番号
US04540732

反応ノート

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