Tributylstannane → 1-(tributylstannyl)-1E-undecen-3-ol

HRID 1722344ノート

反応式

HRID 1722344 の反応式
[CH:1]#[C:2][CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([SnH:17]([CH2:22][CH2:23][CH2:24][CH3:25])[CH2:18][CH2:19][CH2:20][CH3:21])[CH2:14][CH2:15][CH3:16]>>[CH2:22]([Sn:17]([CH2:13][CH2:14][CH2:15][CH3:16])([CH2:18][CH2:19][CH2:20][CH3:21])/[CH:1]=[CH:2]/[CH:3]([OH:12])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:23][CH2:24][CH3:25]

参加物

3

反応物 2

HCID 5948TributylstannaneHCID 2477661-Undecyn-3-ol

生成物 1

HCID 121582911-(tributylstannyl)-1E-undecen-3-ol

反応条件

温度
120 °C

実験手順

To 0.07g (0.42 mmol) of the titled product of Example 7 is added 0.15g (0.5 mmol) of tri-n-butyltin hydride and 20mg of azoisobutyronitrile (AIBN). The reaction mixture was heated to 120°C. for 2 hours. Afterwards, it was cooled to room temperature and pumped at high vacuum overnight. The crude reaction mixture was then heated to 90°C. and maintained at high vacuum for 2 additional hours. Upon cooling to room temperature, the crude product was used as is.

後処理

  1. temperatureAfterwards, it was cooled to room temperature
  2. custompumped at high vacuum overnight
  3. customThe crude reaction mixture
  4. temperaturewas then heated to 90°C.
  5. temperaturemaintained at high vacuum for 2 additional hours
  6. temperatureUpon cooling to room temperature

出典と根拠

ORDレコード
ord-167ca511f3a94596a51c3ca4c0590847
出典データセット
uspto-grants-1989_08
特許番号
US04855324

反応ノート

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