Triethylamine → HCID 86743291、化合物

HRID 1722523ノート

反応式

HRID 1722523 の反応式
Cl[P:2]1[O:7][CH2:6][C:5]([CH3:9])([CH3:8])[CH2:4][O:3]1.[C:10]([C:14]1[CH:15]=[C:16]([CH:44]=[C:45]([C:48]([CH3:51])([CH3:50])[CH3:49])[C:46]=1[OH:47])[CH2:17][C:18]1[C:19]([CH3:43])=[C:20]([OH:42])[C:21]([CH3:41])=[C:22]([CH2:25][C:26]2[CH:31]=[C:30]([C:32]([CH3:35])([CH3:34])[CH3:33])[C:29]([OH:36])=[C:28]([C:37]([CH3:40])([CH3:39])[CH3:38])[CH:27]=2)[C:23]=1[CH3:24])([CH3:13])([CH3:12])[CH3:11].C(N(CC)CC)C>C1(C)C=CC=CC=1>[C:32]([C:30]1[CH:31]=[C:26]([CH:27]=[C:28]([C:37]([CH3:40])([CH3:39])[CH3:38])[C:29]=1[OH:36])[CH2:25][C:22]1[C:21]([CH3:41])=[C:20]([C:19]([CH3:43])=[C:18]([CH2:17][C:16]2[CH:15]=[C:14]([C:10]([CH3:11])([CH3:12])[CH3:13])[C:46]([OH:47])=[C:45]([C:48]([CH3:50])([CH3:49])[CH3:51])[CH:44]=2)[C:23]=1[CH3:24])[O:42][P:2]1[O:7][CH2:6][C:5]([CH3:9])([CH3:8])[CH2:4][O:3]1)([CH3:33])([CH3:34])[CH3:35]

参加物

5

反応物 3

HCID 8471TriethylamineHCID 755081,3,2-Dioxaphosphorinane, 2-chloro-5,5-dimethyl-HCID 162045143,5-Bis(3,5-di-tert-butyl-4-hydroxybenzyl)-2,4,6-trimethylphenol

生成物 1

HCID 86743291HCID 86743291、化合物

試薬・触媒・溶媒 1

HCID 1140Toluene溶媒2 回

実験手順

A solution of 8.45 g of 2-chloro-5,5-dimethyl[1,3,2]dioxaphosphinane in 50 ml of toluene is added dropwise, in the course of 15 minutes and at a temperature between 20° and 30° C., to a solution of 28.65 g of 3,5-bis-[3',5'-ditert.-butyl-4'-hydroxybenzyl]-2,4,6-trimethylphenol and 25.3 g of triethylamine in 150 ml of toluene. The reaction mixture is heated under reflux for 24 hours. After cooling to room temperature, the residue is filtered off and the filtrate is evaporated to dryness. This gives 35 g of a colourless product having a melting point of 190° C.

後処理

  1. temperatureThe reaction mixture is heated
  2. temperatureunder reflux for 24 hours
  3. filtrationthe residue is filtered off
  4. customthe filtrate is evaporated to dryness

出典と根拠

ORDレコード
ord-7386c04e14744a6fb20960458223cb5c
出典データセット
uspto-grants-1989_08
特許番号
US04855345

反応ノート

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