関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Sodium Iodide | HCID 5238 | — |
| 反応物 | Potassium Carbonate | HCID 11430 | — |
| 反応物 | 1-Hexadecanol, 1-(4-methylbenzenesulfonate) | HCID 80171 | — |
| 反応物 | 12-Hydroxystearic acid ethyl ester | HCID 3457651 | — |
| 溶媒 | Acetonitrile | HCID 6342 | — |
| 生成物 | Ethyl 12-palmityloxy-stearate | HCID 86609679 | — |
反応手順
Dissolve 10 mmol palmityl toluene-4-sulfonate, 10 mmol ethyl 12-hydroxystearate, 10 mmol anhydrous potassium carbonate and 0.5 mmol sodium iodide in 100 ml dry acetonitrile and heat to 81° C. with stirring for 6 hours. The reaction is cooled to room temperature. The solvent is evaporated and the products are suspended in MTBE and washed with 3×50 ml cold water. The solvent is evaporated to yield ethyl 12-palmityloxy-stearate.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US07491836B2 |
|---|
| 出典データセット | uspto-grants-2009_02 |
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| ORD ID | ord-a8b16bde96e64d13aeee4dd272f96f0e |
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| 出典メモ | uspto-grants-2009_02 |
|---|
