2,4,6-Tri-tert-butylphenol → HCID 22596552、化合物

HRID 1728780

反応式

HRID 1728780 の反応式
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:6]=1[OH:19])([CH3:4])([CH3:3])[CH3:2].[CH3:20][Al:21](C)C>C(Cl)Cl>[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:6]=1[O-:19])([CH3:4])([CH3:3])[CH3:2].[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([C:15]([CH3:18])([CH3:17])[CH3:16])[C:6]=1[O-:19])([CH3:4])([CH3:3])[CH3:2].[CH3:20][Al+2:21]

参加物

4

反応物 2

HCID 129022,4,6-Tri-tert-butylphenolHCID 16682925Trimethylaluminum

生成物 1

HCID 22596552HCID 22596552、化合物

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

In a sufficiently dried egg-plant type flask provided with a stirrer was sufficiently dried 0.525 g (2 mmol) of 2,4,6-tri-tert-butylphenol recrystallized from hexane. After completion of the drying, 3.3 ml of methylene chloride was added thereto. Then, under nitrogen atmosphere, 0.9 ml (1 mmol) of trimethylaluminum was slowly added dropwise with ice-cooling and stirring, and the mixture was mixed in the dark at room temperature for 1 hour to obtain a methylene chloride solution of methylaluminum bis(2,4,6-tri-tert-butylphenoxide) (mmol/3.3ml).

後処理

  1. customIn a sufficiently dried egg-plant type flask provided with a stirrer
  2. customrecrystallized from hexane
  3. additionAfter completion of the drying, 3.3 ml of methylene chloride was added
  4. temperaturecooling
  5. additionthe mixture was mixed in the dark at room temperature for 1 hour

出典と根拠

ORDレコード
ord-d13f3bf8dcf14b6f8a339ef7020c3d3a
出典データセット
uspto-grants-1994_07
特許番号
US05328970

関連ノート

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