Benzene → HCID 12906807、化合物
反応式
[CH3:1][C:2]1([CH3:7])[NH:6][CH2:5][CH2:4][S:3]1.C1C=CC=CC=1.[Br:14][CH:15]([Br:19])[C:16](Cl)=[O:17].C(N(CC)CC)C>O>[CH3:1][C:2]1([CH3:7])[N:6]([C:16](=[O:17])[CH:15]([Br:19])[Br:14])[CH2:5][CH2:4][S:3]1参加物
6
実験手順
To a mixture of 3.5 g. of 2,2-dimethyl thiazolidine, 50 ml. of benzene and 7.1 g. of dibromoacetyl chloride mixed in an ice bath was added 3.1 g. of triethylamine dropwise with stirring and continued cooling. When reaction was complete, the mixture was poured into water and the benzene layer separated, dried over magnesium sulfate and the benzene removed under vacuum. Yield was 8.5 g. of a dark oil.
後処理
- additionTo a mixture of 3.5 g
- additionwas added 3.1 g
- temperaturecontinued cooling
- customWhen reaction
- customthe benzene layer separated
- dry with materialdried over magnesium sulfate
- customthe benzene removed under vacuum
出典と根拠
- ORDレコード
- ord-683d6c7f294c49fcb8b5e2468f1fc091
- 出典データセット
- uspto-grants-1976_11
- 特許番号
- US03989503
反応ノート
読み込み中…