Hydrochloric Acid → Benzenesulfonyl azide

HRID 1731603

反応式

HRID 1731603 の反応式
[C:1]1([S:7]([NH:10][NH2:11])(=[O:9])=[O:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.Cl.[N:13]([O-])=O.[Na+]>O>[C:1]1([S:7]([N:10]=[N+:11]=[N-:13])(=[O:8])=[O:9])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 65723Benzenesulfonyl hydrazideHCID 23668193Sodium Nitrite

生成物 1

HCID 555606Benzenesulfonyl azide

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

26.3 g of benzenesulphonohydrazide, 100 ml of water, 21 ml of 10N hydrochloric acid and 1.3 g of Emulgator [emulsifier] FD (a fatty alcohol/ethylene oxide addition product) are stirred for 30 minutes, 60 g of ice are added, and a solution of 19.5 g of sodium nitrite in 50 ml of water is then added dropwise in the course of about 30 minutes. The batch is stirred for 30 minutes, excess nitrite is then destroyed with a small amount of sulphamic acid, and excess acid is neutralised with about 5 ml of 10N sodium hydroxide solution. An emulsion of benzenesulphonyl azide is obtained.

後処理

  1. stirringThe batch is stirred for 30 minutes
  2. customexcess nitrite is then destroyed with a small amount of sulphamic acid, and excess acid

出典と根拠

ORDレコード
ord-b6e9a665bb6c475f87f37cf939288ef6
出典データセット
uspto-grants-1986_11
特許番号
US04622391

関連ノート

読み込み中…