化工社化工社 化学情報印刷レポート · 研究参考用
1,3,4,5,6-Pentahydroxyhexan-2-One → GlyTouCan:G09597LJ
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1,3,4,5,6-Pentahydroxyhexan-2-One | HCID 1101 | — |
| 反応物 | L-Fructose | HCID 5460024 | — |
| 生成物 | GlyTouCan:G09597LJ | HCID 24749 | — |
| 生成物 | L-Fructose | HCID 5460024 | — |
反応手順
L-Fructose, which has not been found in nature, was synthesized for the first time by Fischer. See E. Fischer, Ber., 23 (1890) 370-394. DL-Glucose phenylosazone was prepared from α-acrose and hydrolyzed to the glycosulose, which was reduced to DL-fructose. L-Fructose was isolated from the mixture. L-Fructose was later synthesized by Wolfrom and Thompson from L-arabinonic acid in five steps. See M. L. Wolfrom and A. Thompson, Methods of Carbohydr. Chem., 1 (1962) 118-120.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04623721 |
| 出典データセット | uspto-grants-1986_11 |
| ORD ID | ord-546af2674fd24cf8ac43555acbb58e1a |
| 出典メモ | uspto-grants-1986_11 |