化工社化工社 化学情報印刷レポート · 研究参考用
Citral → Citronellal
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Citral | HCID 638011 | — |
| 反応物 | Neral | HCID 643779 | — |
| 生成物 | Citronellal | HCID 7794 | — |
反応手順
The complexes derived from Rh4 (CO)12 or Rh6 (CO)16 and from 1,2-bis-(diarylphosphinomethyl)-cyclobutanes are very particularly suitable for the asymmetric hydrogenation of neral and geranial to give enantiomers of citronellal, because they simultaneously provide a high hydrogenation rate, a good selectivity with respect to citronellal and a good optical purity.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04237072 |
| 出典データセット | uspto-grants-1980_12 |
| ORD ID | ord-939efa0ee4564364a4d5bc2a9d34119b |
| 出典メモ | uspto-grants-1980_12 |