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HRID 1733112作成日:2026年10月26日

19-Hydroxyandrostenedione → 4-Methyl-4,6-androstadiene-3,17,19-trione

https://huagongshe.com/reaction/1733112

反応式

関与物質

役割名称HCID仕込み量
反応物19-HydroxyandrostenedioneHCID 252379—
反応物19-Hydroxy-4-methyl-4-androstene-3,17-dioneHCID 53795050—
反応物17beta,19-Dihydroxy-17alpha-methyl-4-androsten-3-oneHCID 70583258—
反応物17beta,19-Dihydroxy-17alpha-propinyl-4-androsten-3-oneHCID 70583843—
生成物4-Methyl-4,6-androstadiene-3,17,19-trioneHCID 53720057—
生成物17beta-Hydroxy-17alpha-methyl-4,6-androstadiene-3,19-dioneHCID 86735693—
生成物17beta-Hydroxy-17alpha-propinyl-4,6-androstadiene-3,19-dioneHCID 131711096—

反応手順

Following essentially the same procedure and substituting 19-hydroxy-4-methyl-4-androstene-3,17-dione, 17β,19-dihydroxy-17α-methyl-4-androsten-3-one and 17β,19-dihydroxy-17α-propinyl-4-androsten-3-one for the 19-hydroxy-4-androstene-3,17-dione above results in the preparation of 4-methyl-4,6-androstadiene-3,17,19-trione, 17β-hydroxy-17α-methyl-4,6-androstadiene-3,19-dione and 17β-hydroxy-17α-propinyl-4,6-androstadiene-3,19-dione.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US04239681
出典データセットuspto-grants-1980_12
ORD IDord-6ee6896992114d1c966527dd1f25af9d
出典メモuspto-grants-1980_12