2-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)- → alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat

HRID 1733755

反応式

HRID 1733755 の反応式
[CH3:1][C:2]1([CH3:34])[C@@H:4]([CH2:5][C:6](=[N:8][O:9]CC(C)(C)C)[CH3:7])[C@H:3]1[C:15]([O:17][CH:18]([C:32]#[N:33])[C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([O:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[CH:20]=1)=[O:16].[CH3:35][C:36]1(C)[C@@H](CC(=NOCC(C)C)C)[C@H:37]1C(OCC1C=CC=C(OC2C=CC=CC=2)C=1)=O.CC1(C)[C@@H](CC(=NOCC2CC2)C)[C@H]1C(OC(C#N)C1C=CC=C(OC2C=CC=CC=2)C=1)=O.CC1(C)[C@@H](CC(=NOCC2CCC2)C)[C@H]1C(OC(C#N)C1C=CC=C(OC2C=CC=CC=2)C=1)=O.C(C(O)C1C=CC=C(OC2C=CC=CC=2)C=1)#C.C1(=O)N(CO)C(=O)C2CCCCC1=2.ClC1C=CC=C(Cl)C=1CO.CC1C(O)CC(=O)C=1CC=C>>[CH3:34][C:2]1([CH3:1])[C@@H:4]([CH2:5][C:6](=[N:8][O:9][CH:36]([CH3:37])[CH3:35])[CH3:7])[C@H:3]1[C:15]([O:17][CH:18]([C:32]#[N:33])[C:19]1[CH:24]=[CH:23][CH:22]=[C:21]([O:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)[CH:20]=1)=[O:16]

参加物

9

反応物 8

HCID 110832-Cyclopenten-1-one, 4-hydroxy-3-methyl-2-(2-propen-1-yl)-HCID 27156Benzenemethanol, 2,6-dichloro-HCID 78597N-(Hydroxymethyl)-3,4,5,6-tetrahydrophthalimideHCID 129190923-Phenoxy-alpha-ethynylbenzylalcoholHCID 53762777alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylateHCID 544994723-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylateHCID 86737170alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylateHCID 86737171alpha-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate

生成物 1

HCID 53742917alpha-Cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(-2-(isopropoxyimino)propyl)cyclopropanecarboxylat

実験手順

Following procedures similar to Embodiment II above: α-cyano -3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(neopentoxyimino)propyl)cyclopropanecarboxylate, 3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(isobutoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclopropylmethoxyimino)propyl)cyclopropanecarboxylate, α-cyano-3-phenoxybenzyl (1R,cis)-2,2-dimethyl-3-(2-(cyclobutylmethoxyimino)propyl)cyclopropanecarboxylate are prepared as well as the corresponding esters in the racemic and (1R,trans) form and similar esters with other alcohols: α-ethynyl-3-phenoxybenzyl alcohol, 3,4,5,6-tetrahydrophthalimidomethyl alcohol, 2,6-dichlorobenzyl alcohol, 2-chloro-4-phenyl-2-butenl-o1 and allethrolone.

出典と根拠

ORDレコード
ord-ee2702e9dd3e44b1b8632b1eefac668c
出典データセット
uspto-grants-1980_12
特許番号
US04242521

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