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HRID 1738669作成日：2026年10月27日
Triphenylphosphine → (6-Cyano-1,2,3,4-tetrahydro-2-naphthyl)methyltriphenylphosphonium p-toluenesulfonate
https://huagongshe.com/reaction/1738669
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Triphenylphosphine | HCID 11776 | — |
| 反応物 | 5,6,7,8-Tetrahydro-6-[(p-toluenesulfonyl)oxymethyl]-2-naphthalenecarbonitrile | HCID 13488730 | — |
| 生成物 | (6-Cyano-1,2,3,4-tetrahydro-2-naphthyl)methyltriphenylphosphonium p-toluenesulfonate | HCID 21844271 | 55.1% |
反応手順
24.00 g of 5,6,7,8-tetrahydro-6-[(p-toluenesulfonyl)oxymethyl]-2-naphthalenecarbonitrile and 18.38 g of triphenylphosphine were mixed, and then heated at a temperature of 130 to 140° C. for 15 hours in a sealed container. The resulting reaction product was crystallized from an acetone/n-hexane mixture to obtain 23.3 g of the title compound in the form of light yellow powder.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| 特許番号 | US05962695 |
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| 出典データセット | uspto-grants-1999_10 |
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| ORD ID | ord-bca015bab2564a5c86e9833c49467c55 |
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| 出典メモ | uspto-grants-1999_10 |
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