5-Fluoro-1-benzothiophene-2-carboxylic acid → HCID 21841161、化合物

反応式

[F:1]C1C=CC2SC(C(O)=O)=CC=2C=1.F[C:15]1[CH:28]=[CH:27][C:18]2[S:19][C:20]([C:22]([S:24][CH2:25][CH3:26])=[S:23])=[CH:21][C:17]=2[CH:16]=1>>[F:1][C:16]1[C:17]2[CH:21]=[C:20]([C:22]([S:24][CH2:25][CH3:26])=[S:23])[S:19][C:18]=2[CH:27]=[CH:28][CH:15]=1

参加物

反応物 2

HCID 9014395-Fluoro-1-benzothiophene-2-carboxylic acid

HCID 21841166HCID 21841166、化合物2 回

生成物 1

HCID 21841161HCID 21841161、化合物

実験手順

The 5-fluoro-2-benzo[b]thiophenecarboxylic acid prepared above in A was converted to ethyl 5-fluoro-2-benzo[b]thiophenecarbodithioate (mp 91-92° C.) using the procedures described above in Examples 2(B)-2(D). NMR confirmed the structure as that of ethyl 5-fluoro-2-benzo[b]thiophenecarbodithioate.

出典と根拠

ORDレコード: ord-bd946c624e7f4247883a3c35018f4e9b
出典データセット: uspto-grants-1999_10
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05965749

反応ノート

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