2-Methoxy-6-methylaniline → HCID 21836053、化合物

HRID 1739623ノート

反応式

HRID 1739623 の反応式
[F:1][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]([F:18])=[C:4](F)[C:3]=1[F:20].[CH3:21][O:22][C:23]1[CH:29]=[CH:28][CH:27]=[C:26]([CH3:30])[C:24]=1[NH2:25]>>[CH3:21][O:22][C:23]1[CH:29]=[CH:28][CH:27]=[C:26]([CH3:30])[C:24]=1[NH:25][C:4]1[C:3]([F:20])=[C:2]([F:1])[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]=1[F:18].[CH3:21][O:22][C:23]1[CH:29]=[CH:28][CH:27]=[C:26]([CH3:30])[C:24]=1[NH:25][C:4]1[C:3]([NH:25][C:24]2[C:26]([CH3:30])=[CH:27][CH:28]=[CH:29][C:23]=2[O:22][CH3:21])=[C:2]([F:1])[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[C:7](=[O:17])[C:6]=2[C:5]=1[F:18]

参加物

4

反応物 2

HCID 4592492-Methoxy-6-methylaniline2 回HCID 2833793HCID 2833793、化合物

生成物 2

HCID 21836053HCID 21836053、化合物HCID 21836083HCID 21836083、化合物

実験手順

2 g of 1,2,3,4-Tetrafluoroanthraquinone and 25 g of 2-methoxy-6-methylaniline were charged in a 5 cc, four necked flask and then the reaction was carried out at 80° C. for about 4 hours. After completion of reaction, 2-methoxy-6-methylaniline was distilled out from the reaction solution, and a column purification using a column with a silica gel was effected to give rise to 1.04 g of 2-(2-methoxy-6-methylanilino)-1,3,4-trifluoroanthraquinone (Dye 7') (yield 36.7 mol %) and 1.05 g of 2,3-bis(2-methoxy-6-methylanilino)-1,4-difluoroanthraquinone (Dye 20') (yield 28.6 mol %). The physical properties of Dye 7' and analytical values defining the compound are tabulated in Table 23 and the physical properties of Dye 20' and analytical values defining the compound are tabulated in Table 24.

後処理

  1. distillationwas distilled out from the reaction solution
  2. customa column purification

出典と根拠

ORDレコード
ord-47448a32bb304a5eb6296f2b97083110
出典データセット
uspto-grants-1999_10
特許番号
US05968688

反応ノート

読み込み中…