Methanol → HCID 85711145、化合物

HRID 1740345

反応式

HRID 1740345 の反応式
[CH2:1]([N:11]([CH3:22])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].[Br:23][CH2:24][CH2:25][CH2:26][Cl:27].CO>CCCCCC>[Br-:23].[Cl:27][CH2:26][CH2:25][CH2:24][N+:11]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10])([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH3:21])[CH3:22]

参加物

5

反応物 3

HCID 887MethanolHCID 80061-Bromo-3-chloropropaneHCID 818801-Decanamine, N-decyl-N-methyl-

生成物 1

HCID 85711145HCID 85711145、化合物

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

反応条件

温度
65 °C

実験手順

A two-liter, 3-necked, round-bottomed flask equipped with air condensers and a magnetic stirring plate was charged with N,N-didecylmethylamine (65.49 grams, 0.21 moles), 1-bromo-3-chloropropane (33.06 grams, 0.21 moles) and methanol (250 mL). Reaction was maintained at 65° C. for six days. Methanol was removed by rotary evaporation under reduced pressure to yield an oil. To the oil was added hexane (200 mL) causing a white solid to slowly form. The solvent was decanted off from the mixture. The remaining solid dried overnight under vacuum. Yield 81.67 grams 0.17 moles, 82%).

後処理

  1. customA two-liter, 3-necked, round-bottomed flask equipped with air condensers
  2. customReaction
  3. customMethanol was removed by rotary evaporation under reduced pressure
  4. customto yield an oil
  5. customto slowly form
  6. customThe solvent was decanted off from the mixture
  7. customThe remaining solid dried overnight under vacuum

出典と根拠

ORDレコード
ord-ce3ae607adaa4efdbc2a18ca6f1a88d3
出典データセット
uspto-grants-1999_10
特許番号
US05969090

関連ノート

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