Diisobutylaluminum hydride → 3-(2-Pyridyl)-2-propen-1-ol
反応式
CC(C[AlH]CC(C)C)C.[N:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1/[CH:16]=[CH:17]/[C:18](OCC)=[O:19]>C1(C)C=CC=CC=1>[N:10]1[CH:15]=[CH:14][CH:13]=[CH:12][C:11]=1/[CH:16]=[CH:17]/[CH2:18][OH:19]参加物
4
実験手順
As in Example 3, Step 2, but using a 1.5M solution of DIBAL in toluene, the ester from Step 1 of the present example was converted to the title compound. The alcohol was chromatographed on silica using EtOAc/toluene (9:1) as eluent.
出典と根拠
- ORDレコード
- ord-8c2846b9ad0c48d890b85d4f80be9722
- 出典データセット
- uspto-grants-1994_08
- 特許番号
- US05334597
反応ノート
読み込み中…