化工社化工社 化学情報印刷レポート · 研究参考用
Acetic Acid → Adipic Acid
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Nitric Acid | HCID 944 | — |
| 反応物 | Oxygen | HCID 977 | — |
| 反応物 | Cyclohexanone | HCID 7967 | — |
| 触媒 | Cobalt dinitrate | HCID 25000 | — |
| 触媒 | Manganese nitrate | HCID 61511 | — |
| 生成物 | Adipic Acid | HCID 196 | — |
反応手順
A solution containing 25 mmol of cyclohexanone, 0.5 mmol of manganese(II) nitrate, 0.5 mmol of cobalt(II) nitrate and 1.5 mmol of nitric acid in 25 ml of acetic acid was stirred for 5 h at 40° C. in an oxygen atmosphere under ambient pressure. Subsequently, the acetic acid was distilled off. The residue was found to consist mainly of adipic acid with some glutaric acid and a small amount of unreacted starting material. The conversion of cyclo-hexanone was found to be 97.5%, the selectivity of the oxidation to adipic acid being 93.4%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07012155B2 |
| 出典データセット | uspto-grants-2006_03 |
| ORD ID | ord-ea8b88fa6ef14293914a9ca4eb3c2d0d |
| 出典メモ | uspto-grants-2006_03 |