関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Phenylboronic Acid | HCID 66827 | — |
| 反応物 | (2R,3S,4R,5R)-2,3,4,5,6-pentahydroxyhexanal | HCID 107526 | — |
| 反応物 | 2-(Dihydroxyboranyl)benzoic acid | HCID 2733985 | — |
| 反応物 | 1-Ethyl-3-methylimidazolium chloride | HCID 2734160 | — |
| 溶媒 | Dimethylacetamide | HCID 31374 | — |
| 生成物 | D-(-)-Fructose | HCID 5984 | — |
反応手順
Glucose (49.5 mg, 275 μmol), 2-carboxyphenylboronic acid (45.9 mg, 277 μmol) or other phenylboronic acid (as indicated) and MgO (36.6 mg, 908 μmol) were mixed in DMA or [EMIM]Cl (500 mg). The reaction mixture was heated at 120° C. for 4 h. At 1-h intervals, aliquots of the reaction mixture were removed for analysis by HPLC.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US09162999B2 |
|---|
| 出典データセット | uspto-grants-2015_10 |
|---|
| ORD ID | ord-e538e07c080242878556e2b688c7b27b |
|---|
| 出典メモ | uspto-grants-2015_10 |
|---|
