Bromomethyl 4-methoxyphenyl ketone → HCID 15388729、化合物
反応式
[N:1]1[CH:6]=[CH:5][C:4]([C:7]2[S:8][CH2:9][C:10](=[O:13])[NH:11][N:12]=2)=[CH:3][CH:2]=1.[CH3:14][O:15][C:16]1[CH:21]=[CH:20][C:19]([C:22]([CH2:24][Br:25])=[O:23])=[CH:18][CH:17]=1>C(O)C>[Br-:25].[CH3:14][O:15][C:16]1[CH:21]=[CH:20][C:19]([C:22]([CH2:24][N+:1]2[CH:2]=[CH:3][C:4]([C:7]3[S:8][CH2:9][C:10](=[O:13])[NH:11][N:12]=3)=[CH:5][CH:6]=2)=[O:23])=[CH:18][CH:17]=1参加物
4
実験手順
2-(4-Pyridyl)-4H,6H-1,3,4-thiadiazin-5-one (1.88 g, 9.74 mmol) and 4'-methoxyphenacyl bromide (2.23 g, 9.74 mmol) were dissolved in absolute ethanol (40 ml) and stirred at room temperature for one day. The resultingprecipitate was collected by filtration and washed with absolute ethanol toobtain the titled compound (3.84g) as yellow powder.