Phenyl isocyanate → HCID 12876118、化合物
反応式
[CH2:1]([N:3]([CH3:7])[C:4]([NH2:6])=[O:5])[CH3:2].[C:8]1([N:14]=[C:15]=[O:16])[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1>O1CCOCC1>[CH2:1]([N:3]([CH3:7])[C:4]([NH:6][C:15]([NH:14][C:8]1[CH:13]=[CH:12][CH:11]=[CH:10][CH:9]=1)=[O:16])=[O:5])[CH3:2]参加物
4
実験手順
In 50 ml of anhydrous dioxane, 7.7 g (0.075 mole) of 1-ethyl-1-methyl-urea was dissolved, into this solution 8.9 g (0.075 mole) of phenylisocyanate was added dropwise under stirring condition. The reaction was continued at a room temperature for 15 hours, then the precipitate thus formed was obtained by filtration and recrystallized from ethanol to obtain 10.8 g (yield 65%) of 1-ethyl-1-methyl-5-phenylbiuret having a melting point of 157°-159° C.
後処理
- additionwas added dropwise
- customthe precipitate thus formed
- customwas obtained by filtration
- customrecrystallized from ethanol
出典と根拠
- ORDレコード
- ord-3b0b7ff400fd48408ecc41736322347f
- 出典データセット
- uspto-grants-1983_02
- 特許番号
- US04371544
反応ノート
読み込み中…