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llms.txt · MCPガイドプライバシーポリシー · 利用規約 · サポートv1.8.0
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Glycol diglycidyl ether → HCID 131712954、化合物

HRID 1758204
ノート
印刷プレビュー

反応式

HRID 1758204 の反応式
[CH2:1]([N:13]1[C:17](=[O:18])[C:16]2([CH2:23][C:22]([CH3:25])([CH3:24])[NH:21][C:20]([CH3:27])([CH3:26])[CH2:19]2)[NH:15][C:14]1=[O:28])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[O:29]1[CH2:40][CH:30]1[CH2:31][O:32][CH2:33][CH2:34][O:35][CH2:36][CH:37]1[O:39][CH2:38]1>C(O)CCCCCCC.C(OCC)(=O)C>[CH2:1]([N:13]1[C:17](=[O:18])[C:16]2([CH2:19][C:20]([CH3:27])([CH3:26])[N:21]([CH2:38][CH:37]([OH:39])[CH2:36][O:35][CH2:34][CH2:33][O:32][CH2:31][CH:30]([OH:29])[CH2:40][N:21]3[C:22]([CH3:25])([CH3:24])[CH2:23][C:16]4([NH:15][C:14](=[O:28])[N:13]([CH2:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12])[C:17]4=[O:18])[CH2:19][C:20]3([CH3:26])[CH3:27])[C:22]([CH3:25])([CH3:24])[CH2:23]2)[NH:15][C:14]1=[O:28])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

5

反応物 2

HCID 16683Glycol diglycidyl etherHCID 226228223-Dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione

生成物 1

HCID 131712954HCID 131712954、化合物

試薬・触媒・溶媒 2

HCID 9571-Octanol溶媒HCID 8857Ethyl Acetate溶媒

反応条件

温度
180 °C

実験手順

A mixture of 8.6 g of 3-dodecyl-7,7,9,9-tetramethyl-1,3,8-triazaspiro[4.5]decane-2,4-dione and 1.7 g of ethylene glycol bis(2,3-epoxypropyl)ether in 3 ml of octanol was heated to 180° C. for 30 hours. After completion of the reaction, the reaction mixture was dissolved in ethyl acetate and subjected to column chromatography through alumina eluted successively first with diethyl ether, second with a 10:1 by volume mixture of ethyl acetate and triethylamine, and lastly with methanol. The eluate eluted with the last solvent was separated and the solvent was removed therefrom by evaporation under reduced pressure, giving the desired Compound No. 355 in the form of white crystals melting at 74°-76° C.

後処理

  1. customAfter completion of the reaction
  2. washeluted successively first with diethyl ether, second with a 10:1 by volume mixture of ethyl acetate and triethylamine
  3. washThe eluate eluted with the last solvent
  4. customwas separated
  5. customthe solvent was removed
  6. customby evaporation under reduced pressure

出典と根拠

ORDレコード
ord-cc78ed6783994bba8e01801e43aa8c19
出典データセット
uspto-grants-1983_02
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04371644

反応ノート

読み込み中…

このページの内容参加物反応条件実験手順後処理出典と根拠反応ノート