Trimethyl phosphite → Allyl dimethylphosphono-acetate

HRID 1759032

反応式

HRID 1759032 の反応式
C[O:2][P:3]([O:6][CH3:7])[O:4][CH3:5].Cl[CH2:9][C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11]>>[CH3:5][O:4][P:3]([CH2:9][C:10]([O:12][CH2:13][CH:14]=[CH2:15])=[O:11])([O:6][CH3:7])=[O:2]

参加物

3

反応物 2

HCID 8472Trimethyl phosphiteHCID 76206Allyl chloroacetate

生成物 1

HCID 13267138Allyl dimethylphosphono-acetate収率 70.5%

実験手順

191 g of trimethylphosphite were added dropwise under stirring to 188 g of allyl chloroacetate (21/2 h) preliminarly heated to 118°. The reaction mixture was kept at this temperature for 4 h, whereupon it was subjected to a distillation to give 205 g of allyl dimethylphosphono-acetate, b.p. 118°/0.1 Torr.

後処理

  1. temperaturepreliminarly heated to 118°
  2. distillationwas subjected to a distillation

出典と根拠

ORDレコード
ord-1474bf691ca0491282ccf64a8a5dcdd4
出典データセット
uspto-grants-1982_07
特許番号
US04338458

関連ノート

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