関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Ammonia | HCID 222 | — |
| 反応物 | Water | HCID 962 | — |
| 反応物 | But-2-ene | HCID 12220 | — |
| 反応物 | Ammonium iodide | HCID 25487 | — |
| 溶媒 | 1-Butanol | HCID 263 | — |
| 溶媒 | (+-)-2-Butanol | HCID 6568 | — |
| 溶媒 | Methyl Ethyl Ketone | HCID 6569 | — |
| 生成物 | Butylamine | HCID 8007 | — |
| 生成物 | DI-Sec-butylamine | HCID 12277 | — |
| 生成物 | Sec-Butylamine | HCID 24874 | — |
反応手順
A mixture of 18.1 g (1.1 moles) of anhydrous ammonia, 27.5 g (0.5 mole) of cis, trans-2-butenes, 79.1 g of water and 43.5 g (0.10 mole) of ammonium iodide were charged to a 300 cm3 stainless steel autoclave. The autoclave was heated to 335° C. and held there for five hours with agitation; the maximum system pressure was 3,100 psig. A total of 3.3 g of mono-sec-butylamine, 0.01 g of di-sec-butylamine, 0.42 g of mono-n-butylamine, 1.29 g of sec-butyl alcohol, 0.06 g n-butyl alcohol, 0.35 g methylethylketone and 0.93 g of a hydrocarbon oil were obtained, corresponding to a 2-butene conversion of 19.9%, an amines yield of 52.1%, an alcohol yield of 25.9%, MEK yield of 5.0% and an oil yield of 17.0%.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US04827031 |
|---|
| 出典データセット | uspto-grants-1989_05 |
|---|
| ORD ID | ord-11cbb2114530425ca34d27d0563c50cd |
|---|
| 出典メモ | uspto-grants-1989_05 |
|---|
