HCID 20075285、化合物 → HCID 20075273、化合物

反応式

NC1C=CC(C2C=C(C)C=CC=2S(C2C=CC(C)=CC=2C2C=CC(N)=C([N+]([O-])=O)C=2)=O)=CC=1[N+]([O-])=O.[CH2:37]([NH:39][C:40]1[CH:45]=[CH:44][C:43]([S:46]([C:48]2[CH:53]=[CH:52][CH:51]=[CH:50][CH:49]=2)=[O:47])=[CH:42][C:41]=1[N+:54]([O-])=O)[CH3:38]>>[NH2:54][C:41]1[CH:42]=[C:43]([S:46]([C:48]2[CH:49]=[CH:50][CH:51]=[CH:52][CH:53]=2)=[O:47])[CH:44]=[CH:45][C:40]=1[NH:39][CH2:37][CH3:38]

参加物

反応物 2

HCID 20075285HCID 20075285、化合物

HCID 53642139(4-Amino-3-nitrophenyl)-4-methylphenyl sulfoxide

生成物 1

HCID 20075273HCID 20075273、化合物収率 93%

実験手順

Following the procedure described in Example 40 but using as a starting material instead of (4-amino-3-nitrophenyl)-4-methylphenyl sulfoxide a corresponding amount of (4-ethylamino-3-nitrophenyl)-phenyl sulfoxide, the title compound is obtained.

出典と根拠

ORDレコード: ord-829d392fd462458094b2f7cc371c01d0
出典データセット: uspto-grants-1989_05
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04831194

反応ノート

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