(RS) cyano (2,3,4,5,6-pentafluoro-phenyl)methanol → 2,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid

HRID 1762604ノート

反応式

HRID 1762604 の反応式
[CH3:1][C:2]1([CH3:16])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH2:11][CH3:12])=[O:8])[CH:3]1[C:13]([OH:15])=[O:14].[CH3:17][C:18]1([CH3:30])[CH:20]([CH:21]=[CH:22][C:23]([O:25][CH3:26])=[O:24])[CH:19]1[C:27]([OH:29])=[O:28].C(C(C1C(F)=C(F)C(F)=C(F)C=1F)O)#N>>[CH3:16][C:2]1([CH3:1])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH2:11][CH3:12])=[O:8])[CH:3]1[C:13]([OH:15])=[O:14].[CH3:17][C:18]1([CH3:30])[CH:20]([CH:21]=[CH:22][C:23]([O:25][CH3:26])=[O:24])[CH:19]1[C:27]([O-:29])=[O:28]

参加物

5

反応物 3

HCID 23245337(RS) cyano (2,3,4,5,6-pentafluoro-phenyl)methanolHCID 545573312,2-Dimethyl-3-(3-methoxy-3-oxo-1-propenyl) cyclopropanecarboxylic acidHCID 545705842,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid

生成物 2

HCID 545705842,2-Dimethyl-3-(3-propoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acidHCID 867430702,2-Dimethyl-3-(3-methoxy-3-oxo-1-propeny)-cyclopropane-carboxylate

実験手順

Using the procedure of Example 9, (1R, cis, ΔZ)-2,2-dimethyl-3-(3-methoxy-3-oxo-1-propenyl)-cyclopropane-carboxylic acid and (RS) cyano (2,3,4,5,6-pentafluoro-phenyl)methanol were reacted to obtain (RS) cyano (2,3,4,5,6-pentafluoro-phenyl)-methyl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-methoxy-3-oxo-1-propeny)-cyclopropane-carboxylate.

後処理

  1. customwere reacted

出典と根拠

ORDレコード
ord-55cb1781aba7452e8990d374b9b7c09b
出典データセット
uspto-grants-1989_05
特許番号
US04833163

反応ノート

読み込み中…