反応式
[CH3:1][C:2]1([CH3:17])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH:11]2[CH2:13][CH2:12]2)=[O:8])[CH:3]1[C:14]([OH:16])=[O:15].O=C1C2CCCCC=2C(=O)N1CO>>[CH3:1][C:2]1([CH3:17])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH:11]2[CH2:13][CH2:12]2)=[O:8])[CH:3]1[C:14]([OH:16])=[O:15].[CH3:1][C:2]1([CH3:17])[CH:4]([CH:5]=[CH:6][C:7]([O:9][CH2:10][CH:11]2[CH2:13][CH2:12]2)=[O:8])[CH:3]1[C:14]([O-:16])=[O:15]参加物
4
反応物 2
生成物 2
実験手順
Using the procedure of Example 9, (1R, cis, ΔZ) 2,2-dimethyl-3-(3-cycloproplymethoxy-3-oxo-propenyl)-cyclopropane-carboxylic acid and (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl) methanol were reacted to obtain (1,3,4,5,6,7-hexahydro-1,3-dioxo-2H-isoindol-2-yl)-methyl (1R, cis, ΔZ) 2,2-dimethyl-3-(3-cyclopropylmethoxy-3-oxo-1-propenyl)-cyclopropane-carboxylate with a melting point of 102° C. and a specific rotation of [α]D20 =+6.5°±2° (c=0.3% in chloroform).
後処理
- customwere reacted
出典と根拠
- ORDレコード
- ord-6efd580885a24988ba1180a531a849ce
- 出典データセット
- uspto-grants-1989_05
- 特許番号
- US04833163
関連ノート
読み込み中…