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Sodium ethanethiolate → ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Sodium ethanethiolate | HCID 4459711 | — |
| 反応物 | 5,7-dihydro-6H-dibenz[c,e]azepine-6carbonitrile | HCID 19833886 | — |
| 溶媒 | Ethanethiol | HCID 6343 | — |
| 生成物 | ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate | HCID 20041719 | — |
反応手順
starting from 5,7-dihydro-6H-dibenz[c,e]azepine-6-carbonitrile and sodium ethanethiolate in ethanethiol there is obtained ethyl 5,7-dihydro-6H-dibenz[c,e]azepine-6-thiocarboximidate and therefrom with hydrochloric acid in alcohol there is obtained the hydrochloride, m.p. 220° C. (with decomposition);
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04833245 |
| 出典データセット | uspto-grants-1989_05 |
| ORD ID | ord-3da4a351d8e64400a8b8ced28462530c |
| 出典メモ | uspto-grants-1989_05 |