Sodium Sulfide → HCID 86736003、化合物
反応式
[CH2:1]([O:3][C:4]([CH2:6][CH2:7][Sn:8](Cl)(Cl)[CH2:9][CH2:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])=[O:5])[CH3:2].[S-2:18].[Na+].[Na+]>C1(C)C=CC=CC=1>[CH2:1]([O:3][C:4]([CH2:6][CH2:7][Sn:8](=[S:18])[CH2:9][CH2:10][C:11]([O:13][CH2:14][CH3:15])=[O:12])=[O:5])[CH3:2]参加物
4
実験手順
To a solution of 78.4g (0.2 mole) bis(ethoxycarbonylethylene)tin dichloride in 160 ml toluene was added 15.6g (0.2 mole) sodium sulfide as a 40% aqueous solution, while warming the mixture to maintain 85°-90° C. After the completion of the reaction, the layers were separated and the toluene solution of the product vacuum stripped to give the product as a viscous liquid, with refractive index 1.573 at 25° C and infra-red absorption peaks at 1700, 1660, and 1190. The product analyzed 33.9% tin, (C2H5OCOCH2CH2)2SnS requires 33.7% Sn.