Potassium Iodide → HCID 86736004、化合物

反応式

[Cl:1][C:2]([Cl:6])=[CH:3][CH2:4]Cl.[C:7]([O-:16])(=[O:15])[CH2:8][CH2:9][CH2:10][CH2:11][C:12]([O-:14])=[O:13].[K+].[K+].[I-].[K+]>C(N(CC)CC)C>[Cl:1][CH:2]([Cl:6])[CH:3]=[CH:4][O:13][C:12](=[O:14])[CH2:11][CH2:10][CH2:9][CH2:8][C:7]([O:16][CH:4]=[CH:3][CH:2]([Cl:6])[Cl:1])=[O:15]

参加物

実験手順

62 g of 1,1,3-trichloro-propene, prepared according as described in Example 1, were reacted with 36.6 g of potassium adipate for 6 hours at 135° C. in the presence of 2 g of triethylamine and 0.3 g of potassium iodide. The reaction product was then washed and freed of the low-boiling components by means of distillation under vacuum. By a successive molecular distillation (120° C./10-4 mm Hg) 47 g of a substance were obtained which on elementary analysis showed the following composition: