Potassium Iodide → Iodide Ion

HRID 1763891

反応式

HRID 1763891 の反応式
[CH3:1][C:2]([CH2:5][C:6]([C:9]1[CH:14]=[CH:13][C:12]([O:15][CH2:16][CH2:17][O:18][CH2:19][CH2:20][OH:21])=[CH:11][CH:10]=1)([CH3:8])[CH3:7])([CH3:4])[CH3:3].[I-:22].[K+].[I:24]([O-])(=O)=O>O>[CH3:4][C:2]([CH2:5][C:6]([C:9]1[CH:10]=[CH:11][C:12]([O:15][CH2:16][CH2:17][O:18][CH2:19][CH2:20][OH:21])=[CH:13][CH:14]=1)([CH3:7])[CH3:8])([CH3:1])[CH3:3].[I:22][I:24].[I-:24]

参加物

6

反応物 3

HCID 4875Potassium IodideHCID 24775Poly(oxy-1,2-ethanediyl), alpha-((1,1,3,3-tetramethylbutyl)phenyl)-omega-hydroxy-, potassium salt (1:1)HCID 84927Iodate

生成物 2

HCID 30165Iodide IonHCID 131711250Molecular iodine;2-[2-[4-(2,4,4-trimethylpentan-2-yl)phenoxy]ethoxy]ethanol

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

In a suitable glass container is placed 9.9 gm. of octylphenoxypoly(ethyleneoxy) ethanol, dissolved in 50 ml. of water to which is added 0.1 gm. of potassium iodide. The mixture is then acid to a pH of below 3 and 0.02 gm. of iodate ion added with stirring. After standing for twenty-four hours, the solvent is evaporated under vacuum and the formed octylphenoxypoly-(ethyleneoxy)ethanol-iodine is obtained in substantially pure form, without iodide ions.

後処理

  1. waitAfter standing for twenty-four hours
  2. customthe solvent is evaporated under vacuum

出典と根拠

ORDレコード
ord-ae98b13a9023434daef4b43ede3fff5e
出典データセット
uspto-grants-1978_09
特許番号
US04113857

関連ノート

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