Benzaldehyde → 2,3-Diphenylprop-2-enenitrile

HRID 1764541ノート

反応式

HRID 1764541 の反応式
[CH2:1]([C:8]#[N:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH:10](=O)[C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1.O(C(OC)=O)[Na]>CO>[C:2]1([C:1](=[CH:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[C:8]#[N:9])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

参加物

5

反応物 3

HCID 240BenzaldehydeHCID 8794PhenylacetonitrileHCID 178502573HCID 178502573、化合物

生成物 1

HCID 953282,3-Diphenylprop-2-enenitrile

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

12 Grams of benzyl cyanide and 11 grams of benzaldehyde with 10 grams of NaOCOOCH3 are dissolved in 100 mls methanol and refluxed during two hours. The sodium carbonate is collected, hot, on a filter and the solvent is evaporated in a vacuo. There are obtained 22 grams of phenylcinnamonitrile, having Na2CO3 as an impurity. The pure product is obtained by washing with water.

後処理

  1. temperaturerefluxed during two hours
  2. customThe sodium carbonate is collected
  3. filtrationhot, on a filter
  4. customthe solvent is evaporated in a vacuo

出典と根拠

ORDレコード
ord-eafbc63d1ca149a196e1f774f0dfaba8
出典データセット
uspto-grants-1978_09
特許番号
US04116997

反応ノート

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