Diazomethane → Methyl-4-iodocinnamate

HRID 1765697ノート

反応式

HRID 1765697 の反応式
[I:1][C:2]1[CH:12]=[CH:11][C:5]([CH:6]=[CH:7][C:8]([OH:10])=[O:9])=[CH:4][CH:3]=1.[N+](=[CH2:15])=[N-]>CO.C(OCC)C>[CH3:15][O:9][C:8](=[O:10])[CH:7]=[CH:6][C:5]1[CH:4]=[CH:3][C:2]([I:1])=[CH:12][CH:11]=1

参加物

5

反応物 2

HCID 9550DiazomethaneHCID 35997884-Iodocinnamic acid

生成物 1

HCID 582796Methyl-4-iodocinnamate

試薬・触媒・溶媒 2

HCID 887Methanol溶媒HCID 3283Diethyl Ether溶媒

実験手順

A stirred, cooled (ice bath) solution of 4-iodo-cinnamic Acid in methanol was treated with a solution of diazomethane in diethyl ether. The reaction mixture was allowed to warm to ambient temperature, the volatiles were-evaporated in vacuo to afford the title compound.

後処理

  1. customthe volatiles were-evaporated in vacuo

出典と根拠

ORDレコード
ord-885fbbbe44cf4bea960f63f23abe9bbc
出典データセット
uspto-grants-2007_06
特許番号
US07226951B2

反応ノート

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