関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Nitrobenzene | HCID 7416 | — |
| 反応物 | Tetramethylammonium hydroxide dihydrate | HCID 22116808 | — |
| 溶媒 | Benzonitrile | HCID 7505 | — |
| 生成物 | Azoxybenzene | HCID 10316 | 45% |
反応手順
A solution containing 10 g of nitrobenzene, 1.27 g of tetramethylammonium hydroxide dihydrate and 1 g of benzonitrile was stirred at 60° C. with nitrogen bubbled into the solution via a syringe needle for 1 hour. Analysis of a sample of the reaction product by HPLC revealed N-(4-nitrophenyl)-benzamide was produced in 45% yield and azoxybenzene was generated in 22% yield based on tetramethylammonium hydroxide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US05380946 |
|---|
| 出典データセット | uspto-grants-1995_01 |
|---|
| ORD ID | ord-a3dae9cde94f4c1a9997e15f107d85fd |
|---|
| 出典メモ | uspto-grants-1995_01 |
|---|
